Reversible cleavage and formation of the dioxygen OO bond within a dicopper complex

JA Halfen, S Mahapatra, EC Wilkinson, S Kaderli… - Science, 1996 - science.org
A key step in dioxygen evolution during photosynthesis is the oxidative generation of the
OO bond from water by a manganese cluster consisting of M 2 (μ-O) 2 units (where M is …

Surgical management of large AVM's by staged embolization and operative excision

…, LP Carter, RA Flom, PA Raudzens, E Wilkinson - Journal of …, 1987 - thejns.org
✓ A series of 20 patients with giant arteriovenous malformations (AVM's) managed with staged
embolization and surgical resection is presented. Complete excision was accomplished …

Models for nonheme iron intermediates: Structural basis for tuning the spin states of Fe (TPA) complexes

Y Zang, J Kim, Y Dong, EC Wilkinson… - Journal of the …, 1997 - ACS Publications
Our efforts to model the oxygen activation chemistry of nonheme iron enzymes have yielded
transient intermediates with novel properties. These properties can be dramatically affected …

Nonheme Iron Centers in Oxygen Activation: Characterization of an Iron(III) Hydroperoxide Intermediate

M Lubben, A Meetsma, EC Wilkinson… - … Edition in English, 1995 - Wiley Online Library
of coordination. a situation markedly different from porphyrin systems wherc the pyrrole groups
are within the basal plane. Complex 1 has a low-spin iron (r1) center as indicated by the …

A High-valent nonheme iron intermediate. Structure and properties of [Fe2 (. mu.-O) 2 (5-Me-TPA) 2](ClO4) 3

…, G Pan, CR Randall, EC Wilkinson… - Journal of the …, 1995 - ACS Publications
In our efforts to model the oxygen activation chemistry of methane monooxygenase (MMO)
and the R2 protein of ribonucleotide reductase (RNR), we have discovered a transient green …

Structural, spectroscopic, and theoretical characterization of bis (μ-oxo) dicopper complexes, novel intermediates in copper-mediated dioxygen activation

S Mahapatra, JA Halfen, EC Wilkinson… - Journal of the …, 1996 - ACS Publications
A description of the structure and bonding of novel bis(μ-oxo)dicopper complexes and their
bis(μ-hydroxo)dicopper decomposition products was derived from combined X-ray …

Synthetic models of the inactive copper (II)− tyrosinate and active copper (II)− tyrosyl radical forms of galactose and glyoxal oxidases

…, S Mahapatra, LM Berreau, EC Wilkinson… - Journal of the …, 1997 - ACS Publications
A series of Cu II and Zn II complexes with new ligands having either one or two substituted
phenolates appended to the 1,4,7-triazacyclononane frame were prepared and characterized …

Aneurysms of the basilar artery treated with circulatory arrest, hypothermia, and barbiturate cerebral protection

…, LP Carter, PA Raudzens, SA Shedd, E Wilkinson - Journal of …, 1988 - thejns.org
✓ Complete circulatory arrest, deep hypothermia, and barbiturate cerebral protection are
efficacious adjuncts in the surgical treatment of selected giant intracranial aneurysms. These …

Synthetic Modeling of Nitrite Binding and Activation by Reduced Copper Proteins. Characterization of Copper (I)− Nitrite Complexes That Evolve Nitric Oxide

JA Halfen, S Mahapatra, EC Wilkinson… - Journal of the …, 1996 - ACS Publications
In an effort to provide precedence for postulated intermediates in copper-protein-mediated
nitrite reduction, a series of novel complexes containing the Cu I −NO 2 - unit, including …

[HTML][HTML] A certified plasmid reference material for the standardisation of BCR–ABL1 mRNA quantification by real-time quantitative PCR

…, VHJ Van der Velden, P Waits, L Wang, E Wilkinson… - Leukemia, 2015 - nature.com
Serial quantification of BCR–ABL1 mRNA is an important therapeutic indicator in chronic
myeloid leukaemia, but there is a substantial variation in results reported by different …